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IB Chemistry IA idea · Water and the environment

IB Chemistry IA idea: how conductivity changes as water gets saltier

Sea water, estuaries, soup: a conductivity probe turns salt into a number, but not a straight line.

  • Water and the environment
  • SL ideal
  • HL good
  • Lab Extended Essay potential
  • Syllabus: S2.1.2, S1.4.5, S2.4.1, T3

These ideas are starting points, not an IA to copy. Never copy an idea blindly: make the question, method and analysis your own, and check your plan with your teacher.

Example research question

To adapt, never to copy

How does the concentration of sodium chloride solution (0.001, 0.005, 0.01, 0.05, 0.1 and 0.50 mol dm⁻³) affect conductivity (mS cm⁻¹) at 25 °C, and how well does molar conductivity follow Kohlrausch's law?

Change the system, the range or the method so the question is yours. Check it against the research question checklist in our Chemistry IA guide.

Variables

You change
Concentration of sodium chloride solution, 0.001 to 0.50 mol dm-3 (6 or more values, log spacing)
You measure
Conductivity (mS cm-1) and molar conductivity (S cm2 mol-1)
You keep the same
  • Temperature (water bath)
  • Probe calibration and position
  • Cell constant
  • Purity of water used

Method

Prepare serial dilutions of sodium chloride in deionised water at 25 degrees C and record conductivity with a calibrated probe.

Data analysis

Plot conductivity against concentration, then molar conductivity against square root of concentration; compare with Kohlrausch's law and the limiting molar conductivity in a data book; propagate uncertainties.

How it works

You change NaCl concentration (mol dm⁻³) and measure Conductivity (mS cm⁻¹) in NaCl(aq) dilution series, keeping Temperature, Probe calibration, Deionised water the same. Expect a graph of Conductivity / mS cm⁻¹ against NaCl concentration / mol dm⁻³: Rises with concentration, slightly less steeply at high values.

Make it yours

Compare with potassium chloride or magnesium sulfate and relate to ion charge and size.

Extended Essay angle

Test the Debye-Huckel-Onsager equation quantitatively.

Safety

Low hazard solutions.

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